Synthesis of Cycloheptenols from Carbohydrates by Ring-Closing Metathesis
✍ Scribed by Marco-Contelles, José; de Opazo, Elsa
- Book ID
- 126495078
- Publisher
- American Chemical Society
- Year
- 2000
- Tongue
- English
- Weight
- 88 KB
- Volume
- 65
- Category
- Article
- ISSN
- 0022-3263
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📜 SIMILAR VOLUMES
## Abstract For Abstract see ChemInform Abstract in Full Text.
In connection with the synthesis of annonaceous acetogemns and analogs, RCM of unsaturated esters has been studied with the Grubbs benzylidene carbeue catalyst to give 9 to 15 membered lactones in moderate to good yield. Cross metathesis between 2 carbohydrate derivatives and methyl nndec-10-encote
A synthesis of stemoamide has been achieved from D-glucose. The stereocontrolled allylation under Barbier reaction conditions led to the installation of the 2-pyrrolidinone ring at C-3 followed by a ring-closing metathesis approach to construct the azepine ring system.
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