## Ring Closing Metathesis and Cross Metathesis of Carbohydrate Derivatives. -In connection with the synthesis of annonaceous acetoginins, the ring closing metathesis of the carbohydrate-derived unsaturated esters (I) to lactones (II) is detailed. Under similar conditions, cross metathesis betwee
โฆ LIBER โฆ
Ring closing metathesis and cross metathesis of carbohydrate derivatives
โ Scribed by Hanadi El Sukkari; Jean-Pierre Gesson; Brigitte Renoux
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- French
- Weight
- 196 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0040-4039
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โฆ Synopsis
In connection with the synthesis of annonaceous acetogemns and analogs, RCM of unsaturated esters has been studied with the Grubbs benzylidene carbeue catalyst to give 9 to 15 membered lactones in moderate to good yield. Cross metathesis between 2 carbohydrate derivatives and methyl nndec-10-encote is also reported.
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