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Tandem dienyne cross-metathesis/ring-closing metathesis

✍ Scribed by Jason A Smulik; Steven T Diver


Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
73 KB
Volume
42
Category
Article
ISSN
0040-4039

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## Abstract Several dienynes bearing different substituents have been synthesized and subjected to a ring‐closing metathesis (RCM) reaction using ruthenium carbene complexes. Dienynes containing a pre‐existing ring and a quaternary center attached to the alkyne give the expected tandem metathesis p

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## Organo-silicon compounds S 0060 Tandem Dienyne Ring-Closing Metathesis of Alkynyl Silaketals for the Formation of Bicyclic Siloxanes. -Bicyclic siloxanes of varying ring sizes are formed in good to excellent yields using Grubbs' second generation ruthenium catalyst. The symmetrical silaketal su