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Synthesis of cyclic ketones via iron tricarbonyl complexes

✍ Scribed by B.F.G. Johnson; J. Lewis; D.J. Thompson


Publisher
Elsevier Science
Year
1974
Tongue
French
Weight
167 KB
Volume
15
Category
Article
ISSN
0040-4039

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Diene(tricarbonyl)iron complexes linked
✍ Marc Schumacher; Laurence Miesch; Michel Franck-Neumann πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 French βš– 149 KB

Complexed cyclopropyl-3,4-dihydroxyphenylalanine (9 DOPA) were synthesized by diazomethane cyclopropanation of the appropriate diene(tricarbonyl)iron complexes linked to azlactones. Opening of the oxazolone ring by treatment with MeOH and DMAP gave the corresponding methyl esters. Introduction of th