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Synthesis of crown ether–substituted yttrium(III) bisphthalocyanine

✍ Scribed by Yuliya G. Gorbunova; Lyudmila A. Lapkina; Svetlana V. Golubeva; Vladimir E. Larchenko; Aslan Yu. Tsivadze

Book ID
119767952
Publisher
Royal Society of Chemistry
Year
2001
Tongue
English
Weight
70 KB
Volume
11
Category
Article
ISSN
0959-9436

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Semiconductivity and gas-sensing propert
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The conductivity of thin films of crown ether ( 15 -crown-5, 18 -crown-6) substituted lutetium bisphthalocyanines has been studied in the presence of various gases. Under vacuum the films show intrinsic semiconducting propertics \(\left(\sigma \approx 10^{-6} \Omega^{-1}\right.\) \(\left.\mathrm{cm}

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## Abstract An example of the synthesis of substituted crown‐ethers by radical addition reaction of 18‐crown‐6 (1) to several α‐olefins (2a‐e), cyclohexene (2f), vinyl butyl ether (2g), allyl alcohol (2h), trimethylvinylsilane (2i), diethylmaleate (2j) and formaldehyde (2k) in the presence of a per