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Iono-electronics: crown ether substituted lutetium bisphthalocyanines

โœ Scribed by Toupance, Thierry; Ahsen, Vefa; Simon, Jacques


Book ID
120825939
Publisher
The Royal Society of Chemistry
Year
1994
Tongue
English
Weight
250 KB
Volume
1
Category
Article
ISSN
0022-4936

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The conductivity of thin films of crown ether ( 15 -crown-5, 18 -crown-6) substituted lutetium bisphthalocyanines has been studied in the presence of various gases. Under vacuum the films show intrinsic semiconducting propertics \(\left(\sigma \approx 10^{-6} \Omega^{-1}\right.\) \(\left.\mathrm{cm}

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Extensive networks of metastable ions link the major peaks in the electron impact mass spectra of two crown ethers containing 2,6-pyrido units. High-resolution mass measurements and the metastable peaks allow the elucidation of the fragmentation pathways. The spectra are influenced more by the prese