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Synthesis of Cp*2Ti(OTf) and Its Reaction with Water

✍ Scribed by Monty Kessler; Sven Hansen; Dirk Hollmann; Marcus Klahn; Torsten Beweries; Anke Spannenberg; Angelika Brückner; Uwe Rosenthal


Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
287 KB
Volume
2011
Category
Article
ISSN
1434-1948

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Reactions of [(Cp)2Ti(NCS)2] as a potent
✍ Zafar Ahmad Siddiqi; Arif Ali Khan 📂 Article 📅 1995 🏛 Springer 🌐 English ⚖ 268 KB

Bis(cyclopentadienyl)titanium(IV) diisothiocyanate [(Cp)2-Ti(NCS)2 ] reacts with MC12 (M=Cu, Pd or Pt), [CuCI(PPh3)3], [RuC12(PPh3)3] and [RuClz(DMSO)4 ] (DMSO = dimethylsulphoxide) giving solid compounds of stochiometry I-(Cp)2Ti(/~-NCS)zMC12] (M = Cu, Pd or Pt), [(Cp)zTi(p-NCS)2CuCI(PPh3)], [(Cp)2