✦ LIBER ✦

Reactions of [(Cp)2Ti(NCS)2] as a potential metalloligand; synthesis and physico-chemical investigations of novel heterobimetallic complexes

✍ Scribed by Zafar Ahmad Siddiqi; Arif Ali Khan

Publisher: Springer
Year: 1995
Tongue: English
Weight: 268 KB
Volume: 20
Category: Article
ISSN: 0340-4285
DOI: 10.1007/bf00141519

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✦ Synopsis

Bis(cyclopentadienyl)titanium(IV) diisothiocyanate [(Cp)2-Ti(NCS)2 ] reacts with MC12 (M=Cu, Pd or Pt), [CuCI(PPh3)3], [RuC12(PPh3)3] and [RuClz(DMSO)4 ] (DMSO = dimethylsulphoxide) giving solid compounds of stochiometry I-(Cp)2Ti(/~-NCS)zMC12] (M = Cu, Pd or Pt), [(Cp)zTi(p-NCS)2CuCI(PPh3)], [(Cp)2Ti(#-NCS) 2-RuCI(PPh3)2]C1 and [(Cp)2Ti(/~-NCS)2RuC12(DMSO)2]. These products have been characterized by physicochemical and spectroscopic methods.