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Synthesis of chiralN-(ferrocenylalkyl)hydroxylamines

✍ Scribed by Hubert Martin; Rudolf Herrmann; Ivar Ugi

Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
142 KB
Volume
269
Category
Article
ISSN
0022-328X

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πŸ“œ SIMILAR VOLUMES

A convenient synthesis of secondary hydr
A convenient synthesis of secondary hydroxylamines
✍ Ian A O'Neil; Ed Cleator; David J Tapolczay πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 French βš– 95 KB

The oxidation of a range of b-cyanoethyl tertiary amines with mCPBA gives the corresponding N-oxides, which can be isolated or undergo Cope-elimination to give secondary hydroxylamines in excellent yield.