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Synthesis of chiral vinylic sulfoxides by Pd-catalyzed asymmetric sulfinylzincation

โœ Scribed by Naoyoshi Maezaki; Suguru Yagi; Shizuka Ohsawa; Hirofumi Ohishi; Tetsuaki Tanaka


Book ID
108282418
Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
406 KB
Volume
59
Category
Article
ISSN
0040-4020

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โœ Kunio Hiroi; Masayuki Umemura ๐Ÿ“‚ Article ๐Ÿ“… 1992 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 233 KB

Ablracf: A chid a-cyanovinyl sulfoxide served as an efficient chiral enophile in a Lewis acid-catalyzed intramolecular ene reaction. Use of diethylaluminum chloride as a catalyst provided extremely high stereoselectivity in this ene reaction. Based on the stereochemical results obtained, a mechanist