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Pd-Catalyzed Enantioselective C–H Iodination: Asymmetric Synthesis of Chiral Diarylmethylamines

✍ Scribed by Chu, Ling; Wang, Xiao-Chen; Moore, Curtis E.; Rheingold, Arnold L.; Yu, Jin-Quan

Book ID
121416093
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
428 KB
Volume
135
Category
Article
ISSN
0002-7863

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New enantioselective chiral imidazolidin
New enantioselective chiral imidazolidine ligands for Pd-catalyzed asymmetric allylic alkylation
✍ En-Kyung Lee; Sang-Han Kim; B.-H. Jung; Wha-Seung Ahn; Geon-Joong Kim 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 93 KB

Chiral imidazolidine ligands have been synthesized from N,N%-dialkylated cyclohexanediamine derivatives and they were found to act as effective ligands in the palladium-catalyzed asymmetric allylic substitution. The excellent levels of enantiomeric excess up to 98% were obtained in high yield.