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Synthesis of Chiral Sulfamide–Amine Alcohol Ligands for Enantioselective Alkylation of Aldehydes

✍ Scribed by Mao, Jincheng

Book ID
111680852
Publisher
Taylor and Francis Group
Year
2009
Tongue
English
Weight
321 KB
Volume
39
Category
Article
ISSN
0039-7911

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✍ Wei JIN; Yongbo HUANG; Boshun WAN 📂 Article 📅 2010 🏛 Elsevier Science ⚖ 296 KB

Chiral methylsulfonyl-based sulfamide-amine alcohol (SAA) ligands were synthesized from commercially available starting materials in two simple steps. Methylsulfonyl-based SAA ligands catalyzed the asymmetric alkynylation of various aldehydes using alkynylzinc to provide chiral propargyl alcohols wi