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Synthesis of chiral organotin reagents: synthesis of enantiomerically enriched bicyclo[2.2.1]hept-2-yl tin hydrides from camphor. X-Ray crystal structures of (dimethyl)[(1R,2S,4R)-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl]tin chloride and methyl(phenyl)bis[(1R,2S,4R)-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl]stannane

โœ Scribed by Helliwell, Madeleine; Thomas, Eric J.; Townsend, Linda A.


Book ID
118023695
Publisher
Royal Society of Chemistry
Year
2002
Weight
270 KB
Volume
10
Category
Article
ISSN
1472-7781

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In the X-ray crystal structure of 2,2 H -bis((1R,2R,4S)-2-hydroxy-1,3,3-trimethylbicyclo[2.2.1]hept-2-yl)-1,1 H -biphenyl (3-R) fenchyl alcohol units induce a R-sense of asymmetry at the biphenyl axis and support intramolecular hydrogen bonds between the hydroxy groups. Computational ONIOM evaluatio