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Enantioselective hydroformylation of vinyl-aromatics using a rhodium complex with the (1R,2R,4R)-2-(2-diphenylphosphinyl-1,7,7-trimethylbicyclo[2.2.1]hept-2-yl) pyridine

โœ Scribed by Giorgio Chelucci; Mauro Marchetti; Barbara Sechi


Publisher
Elsevier Science
Year
1997
Tongue
English
Weight
367 KB
Volume
122
Category
Article
ISSN
1381-1169

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In the X-ray crystal structure of 2,2 H -bis((1R,2R,4S)-2-hydroxy-1,3,3-trimethylbicyclo[2.2.1]hept-2-yl)-1,1 H -biphenyl (3-R) fenchyl alcohol units induce a R-sense of asymmetry at the biphenyl axis and support intramolecular hydrogen bonds between the hydroxy groups. Computational ONIOM evaluatio