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Synthesis of chiral nonracemic PC(sp3)P pincer ligands

✍ Scribed by Cohen, Orit; Grossman, Olga; Vaccaro, Luigi; Gelman, Dmitri


Book ID
122163626
Publisher
Elsevier Science
Year
2014
Tongue
English
Weight
613 KB
Volume
750
Category
Article
ISSN
0022-328X

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## Abstract **Feel the pinch!** Planar–chiral, cationic, ruthenium–palladium complexes based on η^6^,η^1^‐coordinated ECE′ pincer ligands are synthesized as racemic mixtures by reacting ECE′–palladium complexes and [Ru(C~5~R~5~)(MeCN)~3~]^+^ arenophiles (R=H or Me). Chiral resolution of the cationi