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Synthesis of Chiral Cationic (Diimino- and diaminodiphosphane)ruthenium Complexes and Their Applications in Catalytic Oxidation − Crystal Structures of cis-[RuCl(py){κ4-Ph2PC6H4CH=NC6H10N=CHC6H4PPh2}]BF4 and cis-[RuCl(py){κ4-Ph2PC6H4CH=NC6H10N(H)CH2C6H4PPh2}]BF4

✍ Scribed by Wai-Kwok Wong; Xiao-Ping Chen; Tat-Wai Chik; Wai-Yeung Wong; Jian-Ping Guo; Fu-Wa Lee

Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
180 KB
Volume
2003
Category
Article
ISSN
1434-1948

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📜 SIMILAR VOLUMES

Synthesis, Structural Characterisation a
Synthesis, Structural Characterisation and Reactivity of New Dinuclear Monocyclopentadienyl Imidoniobium and -tantalum Complexes − X-ray Crystal Structures of [{Nb(η5-C5H4SiMe3)Cl2}2(μ-1,4-NC6H4N)], [{Ta(η5-C5Me5)Cl2}2(μ-1,4-NC6H4N)] and [{Ta(η5-C5Me5)(CH2SiMe3)2}2(μ-1,4-NC6H4N)]
✍ Antonio Antiñolo; Iván Dorado; Mariano Fajardo; Andrés Garcés; Isabel López-Sol 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 254 KB

## Abstract The preparation of a family of dinuclear monocyclopentadienyl imidoniobium and ‐tantalum complexes was achieved by two different synthetic routes. The diimido complexes [{M(Cp′)Cl~2~}~2~(μ‐1,__i__‐NC~6~H~4~N)] [Cp′ = η^5^‐C~5~H~4~SiMe~3~, M = Nb, __i__ = 4 (1); Cp′ = η^5^‐C~5~H~4~SiMe~3