Late Transition-Metal Complexes of 2-Ph2PC6H4NHC(O)CH2NHCO2Bz: Observation of Three Distinct Ligation Modes (κ1-P,κ2-P/N and κ3-P/N/N′)
✍ Scribed by Mark R. J. Elsegood; Andrew J. Lake; Martin B. Smith
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 383 KB
- Volume
- 2009
- Category
- Article
- ISSN
- 1434-1948
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## Abstract The complex __trans__‐[RuCl~2~{κ^2^‐__P__,__P__‐(__S__)‐peap}~2~] (1) has been stereoselectively prepared by the treatment of a stoichiometric mixture of complex [RuCl~2~(DMSO)~4~] (DMSO = dimethyl sulfoxide) and (__S__)‐peap [(__S__)‐peap = (−)‐__N__,__N__‐bis(diphenylphosphanyl)‐(__S_
Stepwise introduction of the potential tripod ligands tris(3,5-dimethyl-1-pyrazolyl)borate (Tp\*) and tris(1cyclohepta-2,4,6-trienyl)phosphane into the coordination sphere of rhodium(I) leads mainly to [Tp\*Rh{P(C 7 H 7 ) 3 }] (4), in which Tp\* is linked to the rhodium through a single pyrazolyl gr