Synthesis of chiral bicyclo[4.3.1]decanes via an intramolecular carbonyl ene-reaction
โ Scribed by A. Srikrishna; C. Dinesh; K. Anebouselvy
- Publisher
- Elsevier Science
- Year
- 1999
- Tongue
- French
- Weight
- 242 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0040-4039
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โฆ Synopsis
Synthesis of chiral bicyclo[4.3.1]
decanes via an intramolecular acid catalysed type II ene reaction of chiral (5-isopropenylcyclohex-2-enyl)acetaldehydes derived from (R)-carvone is described.
๐ SIMILAR VOLUMES
## Abstract For Abstract see ChemInform Abstract in Full Text.
Chiral Synthons from Carvone. Part 26. Synthesis of Chiral Bicyclo(3.3. 1)nonanes via a Tandem Intermolecular Alkylation-Intramolecular Michael Reaction Sequence. -A tandem sequence is used for the construction of the title ring system which is present in several natural products. Compound (IIIc)