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Synthesis of chiral bicyclo[4.3.1]decanes via an intramolecular carbonyl ene-reaction

โœ Scribed by A. Srikrishna; C. Dinesh; K. Anebouselvy


Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
242 KB
Volume
40
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


Synthesis of chiral bicyclo[4.3.1]

decanes via an intramolecular acid catalysed type II ene reaction of chiral (5-isopropenylcyclohex-2-enyl)acetaldehydes derived from (R)-carvone is described.


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โœ A. SRIKRISHNA; T. J. REDDY; P. P. KUMAR ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 30 KB ๐Ÿ‘ 1 views

Chiral Synthons from Carvone. Part 26. Synthesis of Chiral Bicyclo(3.3. 1)nonanes via a Tandem Intermolecular Alkylation-Intramolecular Michael Reaction Sequence. -A tandem sequence is used for the construction of the title ring system which is present in several natural products. Compound (IIIc)