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ChemInform Abstract: Chiral Synthons from Carvone. Part 26. Synthesis of Chiral Bicyclo(3.3. 1)nonanes via a Tandem Intermolecular Alkylation--Intramolecular Michael Reaction Sequence.

✍ Scribed by A. SRIKRISHNA; T. J. REDDY; P. P. KUMAR

Publisher: John Wiley and Sons
Year: 2010
Weight: 30 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199746102

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✦ Synopsis

Chiral Synthons from Carvone.

Part 26. Synthesis of Chiral Bicyclo(3.3. 1)nonanes via a Tandem Intermolecular Alkylation-Intramolecular Michael Reaction Sequence.

-A tandem sequence is used for the construction of the title ring system which is present in several natural products. Compound (IIIc) is accompanied by about 60% of a mixture of O-alkylated products. -(SRIKRISHNA, A.; REDDY, T.

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