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Synthesis of Chiral 2-Phospha[3]ferrocenophanes and their Behaviour as Organocatalysts in [3+2] Cyclization Reactions

✍ Scribed by Arnaud Voituriez; Armen Panossian; Nicolas Fleury-Brégeot; Pascal Retailleau; Angela Marinetti


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
329 KB
Volume
351
Category
Article
ISSN
1615-4150

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Chiral Heterospirocyclic 2H-Azirin-3-ami
✍ Simon Stamm; Anthony Linden; Heinz Heimgartner 📂 Article 📅 2003 🏛 John Wiley and Sons 🌐 German ⚖ 326 KB

## Abstract The heterospirocyclic __N__‐methyl‐__N__‐phenyl‐5‐oxa‐1‐azaspiro[2.4]hept‐1‐e n‐2‐amine **(6**) and __N__‐(5‐oxa‐1‐azaspiro[2.4]hept‐1‐en‐2‐yl)‐(__S__)‐proline methyl ester (**7**) were synthesized from the corresponding heterocyclic thiocarboxamides **12** and **10**, respectively, by