The half-sandwich titanium trimethyl complex (η 5 -C 5 H 4 CMe 2 Ar)TiMe 3 (Ar = 3,5-Me 2 C 6 H 3 ) reacts with the Lewis acid B(C 6 F 5 ) 3 to give the ionic Ti IV ansa-cyclopentadienyl-arene complex [(η 5 ,η 6 -C 5 H 4 CMe 2 Ar)TiMe 2 ]-[MeB(C 6 F 5 ) 3 ]. In bromobenzene solvent, addition of more
✦ LIBER ✦
Synthesis of cationic metallocyclophanes with arene and cyclopentadienyl ligands
✍ Scribed by V.S. Kaganovich; A.R. Kudinov; M.I. Rybinskaya
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 671 KB
- Volume
- 323
- Category
- Article
- ISSN
- 0022-328X
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