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Synthesis of cationic arenechromium and cyclopentadienylmanganese dicarbonyl allyl complexes using dienes

✍ Scribed by V. V. Krivykh; O. V. Gusev; P. V. Petrovskii; M. I. Rybinskaya


Book ID
112445696
Publisher
Springer
Year
1983
Tongue
English
Weight
249 KB
Volume
32
Category
Article
ISSN
1573-9171

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Reaction of (1,2-dimethoxyethane)NiBr 2 a with b-iminoamines ligands c-f is reported and produces a series of paramagnetic complexes (b-diimine)NiBr 2 1c-f. Reduction in situ of compounds 1c-f in the presence of 2-methylallyloxyphosphonium salt 2 was found as a one-step synthesis of nickel allyl cat