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Synthesis of casuarine-related derivatives via 1,3-dipolar cycloaddition between a cyclic nitrone and an unsaturated γ-lactone

✍ Scribed by Sebastian Stecko; Jolanta Solecka; Marek Chmielewski


Book ID
108080587
Publisher
Elsevier Science
Year
2009
Tongue
English
Weight
281 KB
Volume
344
Category
Article
ISSN
0008-6215

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1,3-Dipolar cycloadditions of cyclic nit
✍ Pedro de March; Marta Figueredo; Josep Font; Antonio Salgado 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 630 KB

The 1,3-dipolar cycloaddition of cyclic nitrones to several "t-bromo ct,~unsaturated esters and lactones has been studied. All the reactions have shown high stereoselectivity, with a predominance of the endo or exo transition state for the trans or cis dipolarophiles, respectively.