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A DFT study of 1,3-dipolar cycloaddition reactions of 5-membered cyclic nitrones with α,β-unsaturated lactones and with cyclic vinyl ethers: Part 1

✍ Scribed by Sebastian Stecko; Konrad Paśniczek; Carine Michel; Anne Milet; Serge Pérez; Marek Chmielewski

Book ID
108284365
Publisher
Elsevier Science
Year
2008
Tongue
English
Weight
639 KB
Volume
19
Category
Article
ISSN
0957-4166

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1,3-Dipolar cycloadditions of cyclic nit
1,3-Dipolar cycloadditions of cyclic nitrones to γ-bromo α,β-unsaturated esters and lactones
✍ Pedro de March; Marta Figueredo; Josep Font; Antonio Salgado 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 630 KB

The 1,3-dipolar cycloaddition of cyclic nitrones to several "t-bromo ct,~unsaturated esters and lactones has been studied. All the reactions have shown high stereoselectivity, with a predominance of the endo or exo transition state for the trans or cis dipolarophiles, respectively.