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Synthesis of carboxylic esters using formaldehyde dimethyl dithioacetal S,S-dioxide

✍ Scribed by Katsuyuki Ogura; Jun-ichi Watanabe; Hirotada Iida

Book ID: 104244140
Publisher: Elsevier Science
Year: 1981
Tongue: French
Weight: 240 KB
Volume: 22
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)93025-4

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✦ Synopsis

FormaZdehyde dimethyl dithioaceta2 S,S-dioxide ii) reacted with an aZky2 bromide or a 2-aZkeny2 bromide C&J) under phase-transfer conditions using 50% aq. NaOH to give an aZkyZ or 2-alkenyl derivative of 2, whereas, in the reaction tith ,8 in the presence of K C03-KS in HMPA, z formed a I-alken-s-y1 derivative. Transformation of these products into t 8 e corresponding carboxylic esters was also described.

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