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Efficient Addition of Aroyl Radicals to Ketene Dithioacetal S,S -Dioxides and its Utilization in Organic Synthesis

✍ Scribed by Ogura, Katsuyuki; Arai, Takayuki; Kayano, Akio; Akazome, Motohiro

Book ID: 127001152
Publisher: Taylor and Francis Group
Year: 1999
Tongue: English
Weight: 95 KB
Volume: 153
Category: Article
ISSN: 1042-6507
DOI: 10.1080/10426509908546486

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Novel photochemical addition of aromatic

Novel photochemical addition of aromatic aldehydes to ketene dithioacetal S,S-dioxides and its application to organic synthesis

✍ Katsuyuki Ogura; Takayuki Arai; Akio Kayano; Motohiro Akazome 📂 Article 📅 1998 🏛 Elsevier Science 🌐 French ⚖ 268 KB

On irradiation (>290 rim) in the absence or presence of benzophenone, various aromatic aldehydes add to ketene dithioacetal S,S<lioxides to give the corresponding 1:1 adducts, which were shown to be synthetic precursors of indanone derivatives.

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