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Synthesis of Carbon Spheres via a Low-Temperature Metathesis Reaction

✍ Scribed by Pang, Lin-Lin; Bi, Jian-Qiang; Bai, Yu-Jun; Zhu, Hui-Ling; Qi, Yong-Xin; Wang, Cheng-Guo; Han, Fu-Dong; Li, Shao-Jie

Book ID
120465363
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
165 KB
Volume
112
Category
Article
ISSN
1932-7447

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Total synthesis of octalactin A via ring
Total synthesis of octalactin A via ring-closing metathesis reaction
✍ Keith R Buszek; Nagaaki Sato; Youngmee Jeong πŸ“‚ Article πŸ“… 2002 πŸ› Elsevier Science 🌐 French βš– 93 KB

A new total synthesis of the novel lactone natural product octalactin A is described. The key step involves the facile construction of the eight-membered lactone core via ring-closing metathesis (RCM). This oxocene was elaborated to give the powerful antitumor agent octalactin A.