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Synthesis of C-D-E trisaccharide precursors of olivomycin A.

✍ Scribed by Sebesta, David P.; Roush, William R.


Book ID
127006278
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
446 KB
Volume
57
Category
Article
ISSN
0022-3263

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πŸ“œ SIMILAR VOLUMES


Sequential diastereoselective free radic
✍ David Crich; Frank Hermann πŸ“‚ Article πŸ“… 1993 πŸ› Elsevier Science 🌐 French βš– 275 KB

## Sunmuwy: The synthesis of an advanced olivomycin A C-D disaccharide is described in which the snomeric configuration of both 2deoxy-~glycosidic linkages is dek&ned by a quential mective radical reaction at the end of the synthesis.

The Synthesis of an O,C-Trisaccharide: T
✍ Stephen J. Spak; Olivier R. Martin πŸ“‚ Article πŸ“… 2000 πŸ› Elsevier Science 🌐 French βš– 191 KB

The synthesis of an O,C-trisaccharide, namely methyl O-b-d-glucopyranosyl-(134)-C-b-d-glucopyranosyl-(136)-a-dglucopyranoside, was achieved in 14 steps by way of the nitro-aldol coupling of hepta-O-acetyl-b-cellobiosylnitromethane and methyl 6-aldehydo-2,3,4-tri-O-benzyl-a-d-gluco-hexodialdo-1,5-pyr