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Synthesis of C -Aryl-Nucleosides and O -Aryl-Glycosides via Cuprate Glycosylation

โœ Scribed by Hainke, Sven; Singh, Ishwar; Hemmings, Jennifer; Seitz, Oliver


Book ID
126267369
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
150 KB
Volume
72
Category
Article
ISSN
0022-3263

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## Abstract The __N__โ€tetrachlorophthalimidoโ€protected glucosamine donor 2 reacts with electronโ€rich phenol ethers 3aโ€“c to afford aryl Cโ€glycosides 4aโ€“c. The __N__โ€tetrachlorophthaloyl group could be readily removed by sodium borohydride treatment and then phthalide formation or by treatment with e