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Synthesis of C -Aryl and C -Alkyl Glycosides Using Glycosyl Phosphates

โœ Scribed by Palmacci, Emma R.; Seeberger, Peter H.


Book ID
126874046
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
57 KB
Volume
3
Category
Article
ISSN
1523-7060

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## Abstract The __N__โ€tetrachlorophthalimidoโ€protected glucosamine donor 2 reacts with electronโ€rich phenol ethers 3aโ€“c to afford aryl Cโ€glycosides 4aโ€“c. The __N__โ€tetrachlorophthaloyl group could be readily removed by sodium borohydride treatment and then phthalide formation or by treatment with e