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Synthesis of C-3 alkyl analogs of cocaine

โœ Scribed by Shi Xian Deng; Dan Wen Huang; Donald W Landry

Publisher
Elsevier Science
Year
2001
Tongue
French
Weight
63 KB
Volume
42
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

The first general stereocontrolled approach to C-3 alkyl analogs of cocaine is described. The route utilized versatile intermediates 2b-hydroxymethyl-3a-cyanotropane and 2b-hydroxymethyl-3b-cyanotropane.

๐Ÿ“œ SIMILAR VOLUMES

Synthesis of alkylated iridolactone anal
Synthesis of alkylated iridolactone analogs
โœ Zineb Guerrab; Boujemaรข Daou; Souad Fkih-Tetouani; Mohammed Ahmar; Bernard Cazes ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 190 KB

Bicyclic d-lactones, iridolactones analogs with an alkyl group at the bicyclic junction, are obtained from a-alkyl-ahydroxymethylcyclopentanones via an intramolecular Horner-Wadsworth-Emmons reaction.