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Synthesis of bridged tetracyclic systems related to diterpenes through acid-induced intramolecular cyclisation of diazomethyl ketones

โœ Scribed by Sanat K. Maity; Basudeb Basu; Debabrata Mukherjee


Publisher
Elsevier Science
Year
1983
Tongue
French
Weight
137 KB
Volume
24
Category
Article
ISSN
0040-4039

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โœฆ Synopsis


The tetracycllc bridged-ring enones 1, 5 an& 3 have been prepared through acidcatalysed Intramolecular cycllsatlon of the dlazomethyl ketones 11, 16 and 22 respectively for entry Into the ring system of aphldlcolln( 4) and related dlterpenes --


๐Ÿ“œ SIMILAR VOLUMES


Synthesis of bridged carbocyclic systems
โœ Basudeb Basu; Debabrata Mukherjee ๐Ÿ“‚ Article ๐Ÿ“… 1984 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 145 KB

The tricyclic dienediones 5,6 and L have been synthesised for entry into the ring systems of the tetracyclic diterpenes atisiFe;e (\_1\_), phyllocladene (3) and hibaene ( 4) respectively. Atisirene and isoatisirene are tetracyclic diterpenes isolated la from the mod of