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Synthesis of bis(methylcyclopentadienyl)(piperidino)lanthanoids and their catalytic behavior for polymerization of methyl methacrylate

✍ Scribed by Lisheng Mao; Qi Shen; Jie Sun


Book ID
108354588
Publisher
Elsevier Science
Year
1998
Tongue
English
Weight
121 KB
Volume
566
Category
Article
ISSN
0022-328X

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It was first found that (diisopropylamido)bis(methylcyclopentadienyl)lanthanides (MeC 5 H 4 ) 2 LnN(i-Pr) 2 (THF) (Ln Γ… Yb ( 1), Er ( 2), Y (3)) exhibit extremely high catalytic activity in the polymerization of methyl methacrylate. The reactions can be carried out over a quite broad range of polyme