𝔖 Bobbio Scriptorium
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Synthesis of Bis(dimethylamino)carbenetetracarbonyliron

✍ Scribed by Doz. Dr. Wolfgang Petz

Book ID
101545327
Publisher
John Wiley and Sons
Year
1975
Tongue
English
Weight
217 KB
Volume
14
Category
Article
ISSN
0044-8249

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✦ Synopsis

The angles of twist listed in Table 1 for the radicals (3a) to ( 3 c ) , ( 3 e ) and ( 3 f ) can be estimated by comparison with those calculated for twisted benzyl radicals by the INDO method [']. The discrepancy between the experimentally determined angles of twist and those deduced from space filling models, which in the meantime we have also been able to detect in sterically hindered ally1 radicals[1o', shows that the conformation of a molecule can be determined only insuffciently on the basis of its space-filling model.

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