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Synthesis of bisalkenyl ethers by the reaction of 1,1,2,2-tetracyanoethane with α-alkylacroleins in isopropyl alcohol

✍ Scribed by O. E. Nasakin; P. M. Lukin; A. N. Lyshchikov; S. Soro; V. N. Khrustalev; Yu. T. Struchkov


Book ID
112537651
Publisher
Springer
Year
1996
Tongue
English
Weight
173 KB
Volume
45
Category
Article
ISSN
1573-9171

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Use of α-Bromo Oxime Ethers in the Synth
✍ Shatzmiller, Shimon ;Bercovici, Sorin 📂 Article 📅 1992 🏛 John Wiley and Sons 🌐 English ⚖ 563 KB

## Abstract Oxime ethers 1 react with ammonia and primary amines to give α‐amino oxime ethers. The reaction of α‐bromo oxime ethers with sodium azide affords α‐azido oxime ethers. Hydrogenolysis of the azido compounds using 5% palladium on calcium carbonate as catalyst yields the α‐amino oxime ethe