Synthesis of bis-allyloxy functionalized polystyrene and poly (methyl methacrylate) macromonomers using a new ATRP initiator
✍ Scribed by Prakash S. Sane; Dnyaneshwar V. Palaskar; Prakash P. Wadgaonkar
- Book ID
- 113608365
- Publisher
- Elsevier Science
- Year
- 2011
- Tongue
- English
- Weight
- 826 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0014-3057
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## Abstract ω‐Dimethylaminopolystyrenes can be synthesized in quantitative yields by reacting poly(styryl)lithium with 1‐(4‐dimethylaminophenyl)‐1 ‐phenylethylene (1). The resulting polymeric dimethylamino‐substituted 1,1‐diphenylalkyllithium was terminated with methanol or reacted with butadiene t
## Abstract Diblock copolymers of poly(L‐lactide)‐__block__‐poly(methyl methacrylate) (PLLA‐__b__‐PMMA) were synthesized through a sequential two‐step strategy, which combines ring‐opening polymerization (ROP) and atom transfer radical polymerization (ATRP), using a bifunctional initiator, 2,2,2‐tr