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Multifunctional ATRP initiators: Synthesis of four-arm star homopolymers of methyl methacrylate and graft copolymers of polystyrene and poly(t-butyl methacrylate)

✍ Scribed by Polyxeni Moschogianni; Stergios Pispas; Nikos Hadjichristidis


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
127 KB
Volume
39
Category
Article
ISSN
0887-624X

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## Abstract Diblock copolymers of poly(L‐lactide)‐__block__‐poly(methyl methacrylate) (PLLA‐__b__‐PMMA) were synthesized through a sequential two‐step strategy, which combines ring‐opening polymerization (ROP) and atom transfer radical polymerization (ATRP), using a bifunctional initiator, 2,2,2‐tr