Synthesis of biodiesel by Fe(II)-Zn double-metal cyanide complexes
✍ Scribed by Fang YAN; Zhen-hong YUAN; Peng-mei LÜ; Wen LUO; Ling-mei YANG; Li DENG
- Publisher
- Elsevier
- Year
- 2010
- Tongue
- Chinese
- Weight
- 224 KB
- Volume
- 38
- Category
- Article
- ISSN
- 1872-5813
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Neutral transition metal(II) complexes of pyridine-2carbaldehyde pyridin-2'-ythydrazone (papyri) and several analogues have been PrePared by electrochemical synthesis. The [M(papy)2 ] compounds (M = Fe, Co, Ni, Cu or Zn) were obtained mostly as red green dichroic substances as a result of the extend
## Abstract Highly active CaCl~2~‐modified Zn‐Co(III) DMCs were prepared. XRD results showed that the modified catalyst Ca‐DMC containing 0.14 wt.‐% CaCl~2~ was amorphous. A higher polymer yield (>61 kg polymer/g catalyst) and a shorter induction period for ROP of PO were observed for Ca‐DMC than f