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Synthesis of bicyclic imidazole, 1,2,4-triazole and 1,3,5-triazine derivatives fromN-cyanolactam 2-imines

✍ Scribed by Pätzel, Michael ;Bohrisch, Jörg ;Liebscher, Jürgen

Publisher: John Wiley and Sons
Year: 1991
Tongue: English
Weight: 383 KB
Volume: 1991
Category: Article
ISSN: 0947-3440
DOI: 10.1002/jlac.1991199101169

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✦ Synopsis

Abstract

N‐Cyanolactam 2‐imines 1 are versatile NCNC building blocks for the synthesis of partially saturated bicyclic compounds. Reactions with acidic methyl halides, hydroxylamine O‐sulfonic acid, and phenyl isocyanate afford bicyclic imidazole (4), 1,2,4‐triazole (6), and 1,3,5‐triazine (8) derivatives, respectively.

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