## Abstract (−)‐Bicolorin [(1__S__,2__R__,5__R__)‐(−)‐2‐ethyl‐1,5‐dimethyl‐6,8‐dioxabicyclo[3.2.1]octane (1)], the male‐produced pheromone of __Taphrorychus bicolor__, and its (1__R__,2__R__,5__S__) isomer 2 were synthesized by starting from (__S__)‐limonene oxide (3), employing osmium tetroxide ca
Synthesis of (±)-bicolorin, the aggregation pheromone of beech bark beetleTaphrorychus bicolor
✍ Scribed by Astashko, D. A.; Ulashchik, E. A.; Tyvorskii, V. I.
- Book ID
- 121448818
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2013
- Tongue
- English
- Weight
- 203 KB
- Volume
- 49
- Category
- Article
- ISSN
- 1070-4280
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## Abstract The absolute configuration of the new bicyclic acetal 2‐ethyl‐1,5‐dimethyl‐6,8‐dioxabicyclo[3.2.1]octane (1), identified as an aggregation pheromone of males of the beech bark beetle, __Taphrorychus bicolor__, was determined by unambiguous synthesis and NMR experiments. The syntheses of
Synthesis of (1S,2R,5R)-2-Ethyl-1,5-dimethyl-6,8-dioxabicyclo(3.2.1) octane, the Aggregation Pheromone of Male Beech Bark Beetles, Taphrorychus bicolor (Col., Scol.). -An enantioselective synthesis of the title compound (V) is described in order to prove the absolute configuration of the natural pr