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ChemInform Abstract: Synthesis of (1S,2R,5R)-2-Ethyl-1,5-dimethyl-6,8-dioxabicyclo(3.2.1) octane, the Aggregation Pheromone of Male Beech Bark Beetles, Taphrorychus bicolor (Col., Scol.).

✍ Scribed by W. FRANCKE; F. SCHROEDER; U. KOHNLE; M. SIMON

Publisher: John Wiley and Sons
Year: 2010
Weight: 31 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199704248

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✦ Synopsis

Synthesis of (1S,2R,5R)-2-Ethyl-1,5-dimethyl-6,8-dioxabicyclo(3.2.1) octane, the Aggregation Pheromone of Male Beech Bark Beetles, Taphrorychus bicolor (Col., Scol.).

-An enantioselective synthesis of the title compound (V) is described in order to prove the absolute configuration of the natural product. The final cyclization is shown to be dependent on the solvent used. -(FRANCKE, W.;

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