Synthesis of biaryls and arylcarboranes by reacting aryldiazonium fluoborates with aryl- and carboranylcopper
β Scribed by L. I. Zakharkin; A. I. Kovredov
- Book ID
- 112442081
- Publisher
- Springer
- Year
- 1978
- Tongue
- English
- Weight
- 39 KB
- Volume
- 27
- Category
- Article
- ISSN
- 1573-9171
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π SIMILAR VOLUMES
## Abstract A bimetallic catalyst system has been developed that for the first time allows the decarboxylative crossβcoupling of aryl and acyl carboxylates with aryl triflates. In contrast to aryl halides, these electrophiles give rise to nonβcoordinating anions as byproducts, which do not interfer
Aryl radicals are generated by various ways among which thermal decomposition of arenecarbonyl peroxides, 1 arenediazonium salts, 2 acylarylnitrosoamines, 3 and aryl triazenes 4 which are used as efficient precursors for radical reactions. Although they may be useful compounds to generate aryl