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Efficient Synthesis of Sterically Crowded Biaryls by Palladium-Phosphinous Acid-Catalyzed Cross-Coupling of Aryl Halides and Aryl Grignards

✍ Scribed by Wolf, Christian; Xu, Hanhui

Book ID
120785967
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
152 KB
Volume
73
Category
Article
ISSN
0022-3263

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ChemInform Abstract: Efficient Synthesis
ChemInform Abstract: Efficient Synthesis of Sterically Crowded Biaryls by Palladium—Phosphinous Acid Catalyzed Cross-Coupling of Aryl Halides and Aryl Grignards.
✍ Christian Wolf; Hanhui Xu 📂 Article 📅 2008 🏛 John Wiley and Sons ⚖ 29 KB 👁 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

Enantioposition-selective arylation of b
Enantioposition-selective arylation of biaryl ditriflates by palladium-catalyzed asymmetric Grignard cross-coupling
✍ Takashi Kamikawa; Tamio Hayashi 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 869 KB

Asymmetric cross-coupling of achiral biaryl ditriflates with aryl Grignard reagents in the presence of 1 equiv of lithium bromide and 5 tool % of palladium complex PdC12[(S)-alaphos], where alaphos stands for (2dimethylamino)propyldiphenylphosphine, gave axially chiral monophenylation products with