✦ LIBER ✦

Synthesis of biaryl-styrene monomers by microwave-assisted Suzuki coupling

✍ Scribed by Hazit A. Zayas; Michael C. Bowyer; Christopher P. Gordon; Clovia I. Holdsworth; Adam McCluskey

Book ID: 104096829
Publisher: Elsevier Science
Year: 2009
Tongue: French
Weight: 210 KB
Volume: 50
Category: Article
ISSN: 0040-4039
DOI: 10.1016/j.tetlet.2009.07.117

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✦ Synopsis

a b s t r a c t Biaryl-styrenic monomers are prepared via Suzuki coupling as functional monomers in the synthesis of molecularly imprinted polymers. Traditional thermal Suzuki approaches are hampered by competition between Suzuki, Heck and homo-coupling reactions. Microwave-assisted approaches facilitated rapid access to the desired Suzuki products whilst suppressing both Heck and homo-couplings of 4-vinylboronic acid.

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