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Microwave-assisted Suzuki coupling on a KF–alumina surface: synthesis of polyaryls

✍ Scribed by Basudeb Basu; Pralay Das; Md.Mosharef H. Bhuiyan; Satadru Jha

Book ID
104253514
Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
254 KB
Volume
44
Category
Article
ISSN
0040-4039

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✦ Synopsis

A range of conjugated polyaryls has been synthesized through one-pot microwave assisted palladium-catalyzed consecutive Suzuki coupling reactions on a KF-alumina surface with notable features including rapid reaction times, solvent-free conditions, high yields, atom economic and air-insensitive reactions.

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Synthesis of biaryl-styrene monomers by
Synthesis of biaryl-styrene monomers by microwave-assisted Suzuki coupling
✍ Hazit A. Zayas; Michael C. Bowyer; Christopher P. Gordon; Clovia I. Holdsworth; 📂 Article 📅 2009 🏛 Elsevier Science 🌐 French ⚖ 210 KB

a b s t r a c t Biaryl-styrenic monomers are prepared via Suzuki coupling as functional monomers in the synthesis of molecularly imprinted polymers. Traditional thermal Suzuki approaches are hampered by competition between Suzuki, Heck and homo-coupling reactions. Microwave-assisted approaches facil