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Synthesis of Azapyrrolo[3,2,1-jk]carbazoles, Azaindolo[3,2,1-jk]carbazoles, and Carbazole-1-carbonitriles by Gas-Phase Cyclization of Aryl Radicals

✍ Scribed by Crawford, Lynne; McNab, Hamish; Mount, Andrew; Verhille, Jeanne; Wharton, Stuart

Book ID
121528300
Publisher
Thieme Medical Publishers
Year
2010
Tongue
German
Weight
122 KB
Volume
2010
Category
Article
ISSN
0039-7881

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✍ Lynne A. Crawford; Hamish McNab; Andrew R. Mount; Jeanne Verhille; Stuart I. Wha πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 37 KB πŸ‘ 1 views

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4-Hydroxy-5-phenylpyrido[3,2,1-jk]carbazol-6-ones (4, 5), which were obtained from carbazoles 1 and malonates 2 or 3, were converted to reactive intermediates such as 4-chlorides 9 or 4-tosylates 10, which gave in turn 4-azido-5-phenyl derivatives 11. 5-Alkyl-4-azides 11 were not obtained in this ma