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Synthesis of Asymmetric Iron—Pybox Complexes and Their Application to Aziridine Forming Reactions.

✍ Scribed by Mark Redlich; M. Mahmun Hossain

Publisher
John Wiley and Sons
Year
2005
Weight
25 KB
Volume
36
Category
Article
ISSN
0931-7597

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✦ Synopsis

Enantioselective syntheses O 0031

Synthesis of Asymmetric Iron-Pybox Complexes and Their Application to Aziridine Forming Reactions. -Iron-pybox complexes of type (III) are prepared. Their efficiency is tested in the asymmetric aziridination of imines with diazoacetate. Under the optimized conditions shown, cis-aziridines are available in moderate yield and enantioselectivity using ligands (IIIa) and (IIIb).

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