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Synthesis of Arylphosphonates via Palladium-Catalyzed Coupling Reactions of Aryl Imidazolylsulfonates with H-Phosphonate Diesters

✍ Scribed by Luo, Yong; Wu, Jie


Book ID
125838944
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
781 KB
Volume
28
Category
Article
ISSN
0276-7333

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Unsymmetrical biaryls bearing electron-donating and electron-withdrawing functional groups have been obtained in an efficient manner by Pd-catalyzed coupling of aryl halides. Aryl bromides react with aryl iodides to yield unsymmetrical biaryls with marked selectivity.