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Synthesis of Arylated Quinolines by Chemo- and Site-selective Suzuki–Miyaura Reactions of 5,7-Dibromo-8-(trifluoromethanesulfonyloxy)quinoline

✍ Scribed by Nadi Eleya; Ahmed Mahal; Martin Hein; Alexander Villinger; Peter Langer

Book ID: 102690332
Publisher: John Wiley and Sons
Year: 2011
Tongue: English
Weight: 631 KB
Volume: 353
Category: Article
ISSN: 1615-4150
DOI: 10.1002/adsc.201100165

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✦ Synopsis

Abstract

Arylated quinolines were prepared by Suzuki–Miyaura reactions of 5,7‐dibromo‐8‐(trifluoromethanesulfonyloxy)quinoline. The reactions proceed with excellent site‐selectivity. The first, second and third attack occur at positions 5, 7 and 8, respectively.

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