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Synthesis of aryl ortho esters from benzanilide acetals

✍ Scribed by McClelland, Robert A.; Patel, Geeta; Lam, Patrick W. K.


Book ID
120985033
Publisher
American Chemical Society
Year
1981
Tongue
English
Weight
311 KB
Volume
46
Category
Article
ISSN
0022-3263

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πŸ“œ SIMILAR VOLUMES


Alkoxycarbonium ions from acetals and or
✍ Ch.H.V. Dusseau; S.E. Schaafsma; H. Steinberg; Th.J. de Boer πŸ“‚ Article πŸ“… 1969 πŸ› Elsevier Science 🌐 French βš– 181 KB

## Alkoxycarbonium ions can be generated by reaction of BP3 with ortho esters and acetals (1,2). Well resolved NMR-spectra of these ions are obtained in

ESTERS OF ORTHO-ACETIC ACID 1
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Synthesis of ortho-hydroxyacetophenone derivatives 5 was carried out from the reaction of Baylis-Hillman acetates 1 and active methylene compounds 2 in N,N-dimethylformamide in the presence of K 2 CO 3 .